Three ships loaded with grain left Ukrainian ports on Friday (Aug 5) under a recently concluded safe passage deal, the Turkish defenсe ministry and Reuters witnesses said.

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The first grain ship to set sail from a Ukrainian port since the start of the Russian invasion, departed Odesa on Monday.

"We expect that the security guarantees of our partners from the United Nations and Turkey will continue to work, and food exports from our ports will become stable and predictable for all market participants," Ukrainian Infrastructure Minister Oleksandr Kubrakov said on Facebook after the ships set off.

In a rare diplomatic breakthrough in the five-month war, the UN and Turkey have brokered a safe passage deal between Moscow and Kyiv, after the United Nations warned of famines due to Ukrainian grain shipments being halted.

Russian President Vladimir Putin sent troops into Ukraine on Feb 24, sparking the biggest conflict in Europe since World War II and causing a global energy and food crisis. Ukraine and Russia produce about one third of global wheat and Russia is Europe's main energy supplier.

On Friday, two grain ships set off from Chornomorsk and one from Odesa, with a total of about 58,000 tonnes of corn.

The Turkish Defence Ministry said on Twitter the Panama-flagged Navistar, carrying 33,000 tonnes of corn bound for Ireland, departed from Odesa.